That will depend on what metamaterials and how you want to work with them. As a finite-difference time-domain method that directly discretizes the full simulation space if you can created it within that space the product will simulate it. What are you trying to design?
Depending on the materials you are using to design the 1D PC tHis is definitely something that you can do. We do have a number of webinars hosted on the support link that include work with photonic crystals that I would recommend checking out.
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