Dear Alitsu,
This are the symbol points I am giving to the Sequence generator. I have gone through the help section on QAM generator block.
00000
00001
00010
00011
00100
00101
00110
00111
01000
01001
01010
01011
01100
01101
01110
01111
10000
10001
10010
10011
10100
10101
10110
10111
11000
11001
11011
11100
11101
11110
11111
It has all the 32 symbols required for 32QAM generation.